Marimaca Announces Results from Phase 6 Metallurgical Program
News Release
Marimaca Announces Results from Phase 6 Metallurgical Program
Vancouver, British Columbia, November 6, 2023 – Marimaca Copper Corp. (“Marimaca Copper” or the “Company”) (TSX: MARI)
is pleased to announce results of the Phase 6 Metallurgical testing program (the “Phase 6 Program” or the “Program”) for the
Company’s flagship Marimaca Oxide Copper Project (“the MOD” or “the Project”), located in northern Chile.
The Phase 6 program was designed to evaluate leaching conditions to optimize acid consumption, recoveries and leaching
efficiency to be incorporated into the ongoing Definitive Feasibility Study (“DFS”).
Highlights
• Comprehensive 5 column-test program evaluating the impact of curing, leaching rates and acid concentration in solution
on acid consumption, recoveries and impurities generation
• Significantly improved acid consumption based on optimization of leaching conditions
o Net acid consumption of 30.6kg/t from experimental samples – an approximate 25% reduction from the 40.6kg/t
derived from previous metallurgical campaigns
o Provides further confidence in expected acid consumption with clear potential to enhance operating cost profile for
the DFS
• Confirms average copper recovery of 74.9% - in-line with previous results from metallurgical campaigns (Phases 1-5)
• Flexibility for further reductions in acid consumption with relatively low recovery losses
• Program completed with recycled sea-water sourced from Marimaca’s intended water suppl ier under its water option
agreement to accurately reflect process water to be utilized at the Project
• Further de-risking of the Marimaca metallurgy – allows for improved predictability of metallurgical performance during
operations
o Results will be incorporated into the final geo-metallurgical model to be utilized in the DFS which will define, at high
resolution, the metallurgical performance of each ore-feed type in the DFS
• Results demonstrate the self-regulation of impurities in the leaching cycle which allows for simple SX-EW process design
and capital efficiency for the planned DFS
Hayden Locke, President and CEO of Marimaca Copper, commented:
“We are pleased with the Phase 6 metallurgical results and particularly the implications for acid consumption optimization in
the DFS and in future operations.
Acid consumption is a key component of our operating costs, and fluctuations in acid price were identified as a core external
factor in our projected operating margins as we move towards first copper. The results from this program show, firstly, that our
base case assumptions, with respect to acid consumption, can be materially reduced via simple changes to our operational
approach with no significant impact to our expected recoveries.
Secondly, the testing highlights that we have further flexibility to reduce acid consumption, with relatively small recovery losses.
From my perspective, this is the most important outcome from the testing, because it allows us to make operational changes to
preserve margin and cashflow during periods of high acid prices, which increases the resilience of the Project to external shocks.
“The Marimaca Project continues to demonstrate unique positioning in the copper development space. We are excited to move
through the final development milestones as we rapidly advance toward first copper.”
Program Overview
Phase 6 Metallurgy comprised of a set of leaching tests in five 1m high, 6-inch diameter columns. The sample set consisted of
green oxides comprised 50% brochantite/atacamite and 50% chrysocholla with a total sample size of 240kg which was crushed
at P90 ½”, consistent with previous metallurgical test-work phases. The sample was subjected to separation by sieving, in the
½”, ¼”, 10 and -10 Tyler meshes, and then, from each granulometric fraction, a sample size was taken as required to form the
program design cut under the standardized “cut by mono size” technique.
Process seawater used in the column tests was sourced from the counterparty to Marimaca’s water option agreement to
accurately represent the industrial process water that will be used at the Marimaca operation (see Water Option press release
dated November 7, 2022). The leaching conditions were focused on variables to optimize acid consumption. The two variables
controlled were acid dosing in curing step, and the Leaching Ratio (m3 irrigate solution/tonne ore). The head grade of the ore,
the grade of ripios resulting from leaching, the initially acidified seawater, the pregnant leaching solution (“PLS”) and the
raffinate solutions were each characterized by the elements for which the evolution of impurities was monitored. The evolution
of impurities was quantified by determining the concentration in the PLS solutions of the following elements: FeT, Al, Mg, Mn,
Na, Cl- and SO4= and Cu. Cu was removed from the PLS solutions by solvent extraction (SX), at the end of each leaching cycle.
Column Tests
Results were evaluated from two leaching cycles over five columns. In both irrigation cycles, the tests operate in a closed circuit
with a volume of irrigation solution equivalent to 10 days of operation, which, at an irrigation rate of 10 L/h/m 2 is equivalent
to a leaching rate of 0.93m3/to (approximately) for each cycle and 1.86 m3/t in total.
Column 1 (C-1) and Column 2 (C-2) were leached with seawater and acid in the first cycle, then the PLS obtained was treated
by solvent extraction and the raffinate produced was used for the second leaching cycle. The PLS from the second cycle of each
column (C-1 and C-2) was then treated by solvent extraction (SX) and both raffinate solutions produced were mixed and used
as the leaching solution for Column 3 (C-3). The post-SX raffinate of the C-3 PLS was used to leach Column 4 (C-4) and similarly
for C-4 to Column 5 (C-5).
Each column was agglomerated and cured under identical conditions, summarized in Table 3.
Table 1. Sample Set Mass Allocation
Usage Unit Value
Columns kg 150 (5x30kg)
Head Grade kg 10
Back Up kg 80 (4x20kg)
Table 2. Particle Size Distribution of Sample Set
Granulometric
Fraction
Mass (kg)
C-1 C-2 C-3 C-4 C-5 Backup
1/2" 3.25 3.25 3.25 3.25 3.25 8.66
1/4" 9.51 9.51 9.51 9.51 9.51 25.37
+10 # 8.62 8.62 8.62 8.62 8.62 22.97
-10 # 8.62 8.62 8.62 8.62 8.62 22.99
TOTAL 30.0 30.0 30.0 30.0 30.0 80.0
Table 3. Agglomeration and Curing Conditions
Parameter Unit Value
Moisture (Seawater) % 6
Acid Dose Curing kg/ton 20
Curing Time days 3
Following the irrigation cycle in each column, t he solution contained inside the column was allowed to drain, and the ripios
were washed by passing a seawater solution at pH 3 at an irrigation rate of 10 L/h/m2 for 24 hours. The drained volume was
measured and analyzed for the same elements considered in the analysis of the PLS solutions.
Following drainage of the washing stage, the ripios were unloaded from the respective columns and the wet and dry weights
were recorded. A subsample equal to a quarter of the total ripios sample was sent for chemical assays following separation.
Results
Acid Consumption
Acid consumption was measured by both total acid consumption (CAB) and net acid consumption (CAN). CAN reflects acid
consumed only by the gangue minerals (carbonate, aluminium, total iron, magnesium) given raffinate is recirculated with the
acid consumed by copper post the SX stage. Geomet 6 was designed to evaluate the optimization of acid consumption by
evaluating three variables: acid curing rate (20kg/t), acid concentration (10gpl) and leaching ratio (1.86m3/t).
Results of the column test acid consumption is presented in Figure 1. Average CAB was 36.91kg/t while average CAN was
30.63kg/t.
Figure 1. Acid Consumption – Columns 1-5
By controlling the noted variables, acid consumption can be optimized given the sequential nature of consumption by each of
the gangue minerals – for example, the majority of acid consumption in the curing stage is driven by carbonate , followed by
copper, aluminum, total iron and magnesium predominantly during the leaching cycle.
Copper Recovery
Table 4 and Figure 2 show the calculated head and head/ripio base copper recovery by columns. The average copper recovery
of the 5 columns per head calculated was 74.9%, while the recovery per head/ripios was 73.0%. Results are in-line with expected
results based on previous test-work and demonstrate that copper recovery can be maintained while optimizing the variables
that reduce acid consumption and impurities generation.
Table 4. Column Recoveries
Column
Analyzed
Cu Head
Grade
Calculated Cu
Head Grade
Fine Cu
Analyzed
Head Grade
Copper
Leached
Copper in
Ripios
Copper
Calculated
Head
Recovery
Calculated
from Head
(R CC)
Recovery
Calculated
from Ripios
(R C/R)
(N°) (%) (%) (g) (g) (g) (g) (%) (%)
C-1 0.620 0.568 186.00 122.64 47.74 170.4 72.0 74.3
C-2 0.620 0.628 186.00 139.47 49.03 188.4 74.0 73.6
C-3 0.620 0.638 186.00 143.68 47.74 191.4 75.1 74.3
C-4 0.620 0.718 186.00 166.72 48.83 215.4 77.4 73.7
C-5 0.620 0.815 186.00 186.3 58.05 244.5 76.2 68.8
C-1 C-2 C-3 C-4 C-5 Global
CAB 40.11 40.57 28.15 43.53 32.19 36.91
CAN 35.50 35.05 20.96 36.70 24.95 30.63
0.0
5.0
10.0
15.0
20.0
25.0
30.0
35.0
40.0
45.0
50.0Consumo de Ácido (kg/t)
Column
Acid Consumption
Figure 2. Column Recoveries
Impurities Generation
The column tests were evaluated to determine the experimental evolution of impurities generation vs. the theoretical evolution
of impurities generation to determine the equilibrium point of the system. This was studied to determine the expected
performance of the SX-EW plant and its ability to handle the solution generation from leaching of Marimaca ores.
Results shows that as the recirculation of leaching solution occurs, as is the case in industrial operations, the capacity of the
system to dissolve impurities decreases, which indicates that the system self -regulates before any impurities mitigation is
required in the SX-EW process design. In industrial terms, by feeding the heap with fresh ore, the curing acid and the leaching
solutions will dissolve new impurities, but simultaneously others will precipitate in the heap , and the system will reach
equilibrium.
This concept is demonstrated in Figure 3. Whereby results from Geomet 6 show the experimental sulfate concentration in each
cycle deviates and plateaus relative to the theoretical sulfate concentration with the correlation coefficient of the experimental
results of 0.9992. When projecting the experimental curve 3 additional cycles, it can be observed that the sulfate saturation
level is approximately 147 gpl.
Table 5. Evolution of Impurities Concentration in PLS solution
Column FeT Al+3 Mg+2 Mn+2 Na+ Cl- SO4=
(Nº) (g/L) (g/L) (g/L) (g/L) (g/L) (g/L) (g/L)
C-1 6,54 3,14 3,49 0,25 13,15 27,55 46,21
C-2 6,18 3,03 3,21 0,20 12,55 26,67 44,76
C-3 9,61 5,40 4,03 0,37 13,42 28,81 74,98
C-4 13,50 6,99 5,61 0,57 16,05 31,43 103,37
C-5 17,52 10,34 6,80 0,80 18,53 38,16 120,32
C-1 C-2 C-3 C-4 C-5 Global
R CC 72.0 74.0 75.1 77.4 76.2 74.9
R C/R 74.3 73.6 74.3 73.7 68.8 73.0
0.0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0Copper Recovery (%)
Columns
Copper Recovery
Figure 3. Evolution of Sulfate Concentration in PLS solution
Appendix: Chemical Characterization of Experimental Inputs
Below the chemical characterization of the head sample, the seawater input, and the leaching solution are presented.
Table 6. Chemical Characterization of Head Sample
Elements
CuT
(%)
FeT
(%)
Al
(%)
Mg
(%)
Mn
(%)
Na
(%)
CO3
(%)
Cl-
(%)
SO4=
(%)
Head Grade 0.641 7.66 6.72 1.05 0.07 3.09 0.63 0.25 0.15
Table 7. Chemical Characterization of Seawater Used
Element
Cu+2
(mg/L)
FeT
(mg/L)
Al+3
(mg/L)
Mg+2
(g/L)
Mn+2
(mg/L)
Na+
(g/L) Cl- (g/L)
SO4=
(g/L)
pH
Seawater 0,00 0,90 1,70 1,44 ND 11,33 23,21 2,10 7,60
Table 8. Chemical Characterization of the Initial Leaching Solution (for Columns C-1 and C-2)
Cu+2 FeT Fe+2 Al+3 Mg+2 Mn+2 Na+ Cl- H+ pH SO4=
(mg/L) (mg/L) (mg/L) (mg/L) (g/L) (mg/L) (g/L) (g/L) (g/L) (g/L)
Leach
Solution 0,00 0,90 ND 1,70 1,44 ND 11,33 22,10 9,38 0,75 9,94
y = -2.7354x2 + 44.277x - 31.922
R² = 0.9992
0
20
40
60
80
100
120
140
160
0 2 4 6 8 10
Concentration (gpl)
Column + Modelled Column
Sulfate Dissolution
SO4= (T)
SO4= (E)
Qualified Person
The Qualified Person for technical information in this news release is Gabriel Vera, an extractive metallurgical engineer with
over 35 years of experience . Mr. Vera is a registered member of the Comision Minera (Chilean Mining Commission) and a
Qualified Person for the purposes of NI 43-101.
The QP confirms they have reviewed and approved the scientific and technical information related to metallurgy in this news
release.
Contact Information
For further information please visit www.marimaca.com or contact:
Tavistock
+44 (0) 207 920 3150
Gareth Tredway / Adam Baynes
Forward Looking Statements
This news release includes certain “forward-looking statements” under applicable Canadian securities legislation. There can be
no assurance that such statements will prove to be accurate, and actual results and future events could differ materially from
those anticipated in such statements. Forward-looking statements reflect the beliefs, opinions and projections on the date the
statements are made and are based upon a number of assumptions and estimates that, while considered reasonable by
Marimaca Copper, are inherently subject to significant business, economic, competitive, political and social uncertainties and
contingencies. Many factors, both known and unknown, could cause actual result s, performance or achievements to be
materially different from the results, performance or achievements that are or may be expressed or implied by such forward -
looking statements and the parties have made assumptions and estimates based on or related to ma ny of these factors. Such
factors include, without limitation: risks related to share price and market conditions, the inherent risks involved in the mining,
exploration and development of mineral properties, the uncertainties involved in interpreting dril ling results and other
geological data, fluctuating metal prices, the possibility of project delays or cost overruns or unanticipated excessive operating
costs and expenses, uncertainties related to the necessity of financing, uncertainties relating to regulatory procedure and timing
for permitting reviews, the availability of and costs of financing needed in the future as well as those factors disclosed in the
annual information form of the Company dated March 27, 2023 and oth er filings made by the Company with the Canadian
securities regulatory authorities (which may be viewed at www.sedar.com). Statements regarding the Company’s planned DFS
on the Project are forward-looking information and may not be realized. Readers should not place undue reliance on forward-
looking statements. Marimaca Copper undertakes no obligation to update publicly or otherwise revise any forward- looking
statements contained herein whether as a result of new information or future events or otherwise, except as may be required
by law.
Neither the Toronto Stock Exchange nor the Canadian Investment Regulatory Organization accepts responsibility for the
adequacy or accuracy of this release.