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LITH.V ·

Lithium Chile Provides Operational Update ON the Phase TWO Development Program ON Its Salar de Arizaro Project Located IN Salta Province, Argentina Where Field Tests from the First Step Out Well Returned Lithium Grades IN Excess of 340 Mg/L

Mine Development & Operations Exploration Programs

LITHIUM CHILE PROVIDES OPERATIONAL UPDATE ON THE PHASE TWO DEVELOPMENT PROGRAM ON

ITS SALAR de ARIZARO PROJECT LOCATED IN SALTA PROVINCE, ARGENTINA WHERE FIELD TESTS FROM

THE FIRST STEP OUT WELL RETURNED LITHIUM GRADES IN EXCESS OF 340 MG/L

TSX Venture Exchange: LITH For Immediate Release

OTC-BB: LTMCF

CALGARY, ALBERTA, September 14, 2022 – Lithium Chile Inc. (“Lithium Chile” or the “Company”) is

pleased to announce that it has field tested 340 mg/l from the first hole of its Phase Two development

program at Salar de Arizaro (“Arizaro”) - and that all aspects of the development program are

progressing well. The Phase Two development program is designed to increase the Company’s

previously announced 1,420,000 metric tonne lithium carbonate resource and to expand the

commercial potential of the Arizaro project.

PROGRAM HIGHLIGHTS:

 340 mg/l in the first exploration hole is 14% higher than the resource grade used in the

Company’s maiden resource report;

 Completed two of four planned exploration holes with a third hole underway;

 First of three planned production holes has commenced;

 Critical fresh water well completed encountering 100 metre fresh water aquifer;

 Metallurgical studies underway to determine best lithium extraction process.

Exploration Holes - Highlights:

The Company has completed the first two holes of its planned four-hole diamond drill program and is

250 metres into the third hole (See Figure 1 for hole locations).

The first hole was drilled approximately 5 kilometers away from the initial production test well yet

encountered the brine aquifer at 357 metres, 25 metres deeper than the initial hole. The formation was

still open in coarse black sands when drilling stopped at 465 metres as a result of the drilling rig capacity.

Industry accepted field sampling was done using the Company’s Turbospec lithium analyzer and

returned assays of 340 mg/ litre of lithium. This grade was 14% greater than the 298 mg/l lithium grade

used in the initial 43-101 report. Assay results are pending from the laboratory which will ultimately

form the basis of an updated NI 43-101 resource report.

The second hole had a thicker halite cap then encountered in the first hole and drilling was suspended at

400 metres. The hole will be completed using our larger rotary rig which is capable of drilling to 800

metres.

The third hole, located on the northern extension of the Company’s Arizaro claims, is currently at 250

metres. The halite cap appears thinner on the northern claims and consists of broken halite, mixed with

sands and was encountered at shallower depths. Sampling has begun using a double packer system to

ensure the most accurate results.

Diamond Drill Rig on the Salar de Arizaro

Production Holes - Highlights:

The large rotary drilling rig arrived on site two weeks ago and is currently drilling the first of the three

production wells planned for this program (See Figure 1 for hole location). As this rig is capable of

deeper drilling, the Company plans to drill an 18 inch diameter well to accommodate a 16 inch down

hole pump, to a significantly deeper depth of 800 metres. Drilling is presently proceeding through 160

metres depth on this initial production well. The Company is completing a concurrent baseline

environment impact study for a 5,000 metric tonne-per-year production facility for the three production

wells that will be available after completion of the Phase Two development program which are expected

to be completed early in the first quarter of 2023.

Rotary Rig on the Salar de Arizaro

Metallurgical Studies:

The Company is conducting metallurgical studies on 2,000 litres of brine collected from the first

production well completed in the First Phase Program. These tests include advanced chemistry studies

at the Company’s recently established lab in Jujuy Province to determine best production processes for

lithium extraction, conducting evaporation tests to determine concentrations that will yield optimum

recovery of lithium. Evaporation tests will also allow for the precipitation of impurities associated with

these brines. The Company has also delivered 150 litres of brine to Chengxin’s DLE facility in China for

production tests. Lithium Chile is also in the process of shipping brines to Summit Nanotech’s facility in

Calgary, Alberta for initial analysis.

Metallurgy studies conducted on brine collected from the Company’s first production well in there recently

established lab.

Test evaporation pools to determine best production concentrations using brine collected from the Company’s

first production well

Water Well:

The Company’s first, fresh water well has been drilled, completed, and cased on the southern border of

the Salar de Arizaro. Over 100 metres of freshwater aquifer was identified. Testing has now begun on

flow rates and recharge rates and this data will be submitted to the Salta Provincial Water Ministry in

support of a future application to use a percentage of the water for lithium carbonate production.

Water Well on the Salar de Arizaro

Mobile Camp:

The Company’s camp on the Salar de Arizaro has been expanded to accommodate 50 employees as a

result of significantly expanded operations currently underway. The camp is complete with a kitchen,

dining room and health & safety modules. The on-site camp allows for non-stop operations and

significantly reduces the Company’s travel costs.

On-site camp at the Salar de Arizaro

Steve Cochrane, President & CEO comments, “I am very pleased with the progress we have made to

date expanding our Arizaro project and its potential resource, on time and on budget. I am also very

proud of our team on the ground in Salta and on Arizaro; they have accomplished everything we could

have asked for in developing the Arizaro project and proving it has the potential to be the next big

lithium resource in Argentina”.

Figure 1 Phase Two Program - Well Locations, Arizaro, Argentina

CHILEAN UPDATE

Pursuant to the recent NO vote on the proposed new constitution for Chile having occurred a week ago,

Lithium Chile has already seen an increased interest in their Chilean assets. The Company has recently

designed a 74-kilometer TEM geophysical program on its Llamara lithium prospect in Chile. The contract

has gone out for tender, and the program is planned to get underway in the next month. Llamara has

historic drill results showing lithium brines on the property with lithium grades up to 343 mg/l.

Assay Locations, Llamara, Chile

The Company announces that it has implemented an Equity Incentive Compensation Plan (the "Plan").

The Plan is a "fixed 10%" security-based compensation plan under TSX Venture Exchange (the

"Exchange") policies, pursuant to which 19,612,185 awards may be granted. The Company received

disinterested shareholder approval for the Plan at the Company's annual general and special meeting

held on June 28, 2022, and approval from the Exchange on August 23, 2022.

The Company has granted an aggregate of 4,000,000 restricted share units (each, an "RSU") to two

executive officers of the Company. The RSUs vest one year from the date of the grant, and each RSU

will entitle the holder to receive one common share of the Company for a period of five years.

Qualified Person, QA/QC Statements:

Michael Rosko, MS, PG, of Montgomery and Associates (M&A) of Santiago, Chile, is a registered

geologist (CPG) in Arizona, California and Texas, a registered member of the Society for Mining,

Metallurgy and Exploration (SME No. 4064687), and a qualified person as defined by National

Instrument 43-101. Mr. Rosko has extensive experience in salar environments and has been a qualified

person on many lithium brine projects. Mr. Rosko and M&A are completely independent of Lithium

Chile. Mr. Rosko has reviewed and approved the scientific and technical content of this news release.

About Lithium Chile

Lithium Chile is advancing a lithium property portfolio consisting of 81,300 hectares covering sections of

11 salars and 2 laguna complexes in Chile and 23,300 hectares in Argentina.

Lithium Chile also owns 5 properties, totaling 21,329 hectares that are prospective for gold, silver and

copper. Exploration efforts are continuing on Lithium Chile’s Carmona gold/silver/copper property

which lies in the heart of the Chilean mega porphyry gold/ silver/copper belt.

Lithium Chile’s common shares are listed on the TSX-V under the symbol “LITH” and on the OTC-BB

under the symbol “LTMCF”.

To find out more about Lithium Chile Inc., please contact Steven Cochrane, President and CEO via email:

[email protected] or Michelle DeCecco, Vice President of Corporate Development via email

[email protected] or at 403-390-9095.

Forward Looking Statements

NEITHER THE TSX VENTURE EXCHANGE NOR ITS REGULATION SERVICES PROVIDER (AS THAT TERM IS

DEFINED IN THE POLICIES OF THE TSX VENTURE EXCHANGE) ACCEPTS RESPONSIBILITY FOR THE

ADEQUACY OR ACCURACY OF THIS RELEASE.

NOT FOR RELEASE IN THE UNITED STATES

This news release may contain certain forward-looking information and forward-looking statements within the

meaning of applicable securities legislation (collectively "forward-looking statements"). Generally, forward-looking

statements can be identified by the use of forward-looking terminology such as "expected", "anticipated", "aims

to", "plans to" or "intends to" or variations of such words and phrases or statements that certain actions, events or

results "will" occur. Such forward-looking statements are based on various assumptions and factors that may

prove to be incorrect, including, but not limited to, factors and assumptions with respect to: the general stability of

the economic and political environment in which the Company operates; the timely receipt of required regulatory

approvals; the risk that the new lithium exploration tender processes does not yield the anticipated benefits to the

Company; the ability of the Company to obtain future financing on acceptable terms; currency, exchange and

interest rates; operating costs; the success the Company will have in exploring its prospects and the results from

such prospects and the COVID-19 pandemic. LFG. You are cautioned that the foregoing list of material factors and

assumptions is not exhaustive. Although the Company believes that the assumptions and factors on which such

forward-looking statements are based upon are reasonable, undue reliance should not be placed on the forward-

looking statements because the Company can give no assurance that they will prove to be correct or that any of

the events anticipated by such forward-looking statements will transpire or occur, or if any of them do so, what

benefits the Company will derive there from. The Company does not undertake to update any forward-looking

statements herein, except as required by applicable securities laws. All forward-looking statements contained in

this news release are expressly qualified by this cautionary statement.