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LITH.V ·

Lithium Chile Commences Phase TWO of the Resource Expansion Program ON Their Salar de Arizaro Project.

Exploration Programs

LITHIUM CHILE COMMENCES PHASE TWO OF THE RESOURCE EXPANSION

PROGRAM ON THEIR SALAR DE ARIZARO PROJECT.

TSX Venture Exchange: LITH For Immediate Release

OTC-BB: LTMCF

CALGARY, ALBERTA, February 14, 2022 – Lithium Chile Inc. (“Lithium Chile” or the

“Company”) is pleased to announce it has commenced their phase 2 drilling program

consisting of three, 500-metre-deep step-out holes aimed at expanding the lithium resource

and increasing the grade on the Arizaro property. The program is announced after an initial

resource of 1,420,000 tonnes of lithium carbonate (“Li2CO3”) equivalent in the Indicated

and Inferred Resource categories was reported on their maiden well (see February 8, 2022

News Release). Well permitting and an environmental impact study are currently underway.

Drilling of the first well is anticipated by the end of March. The 3 well program is scheduled

to take 6 months.

As recommended by the company's QP, Montgomery & Associates, steel casing will be

installed down the wellbore and the upper halite will be cemented off to prevent dilution by

lithium-poor brine from the upper zones. On the Company’s initial well, samples during

various tests returned values up to 555 mg/ls.

Steve Cochrane, President and CEO of Lithium Chile, commented on the Salar de Arizaro

Project: “After such encouraging results on the NI 43-101 resource estimate of our maiden

well, the important next steps for our Company and its Shareholders are to expand the

lithium resource and prove the overall grade with the phase 2 drilling program on the Arizaro

property. As a result of our deep relationships with the Argentina community, we have

secured a drilling rig for the duration of the project, which we estimate to take around 6

months”

Phase 2 – Well Locations

The Company also reports on their successful Warrant Program. An additional 1,959,043

common shares have been issued in consideration of C$1,175,425 as the result of the

exercise of outstanding warrants. A total of 3,789,528 Warrants from the February 23, 2021,

financing remain outstanding at C$0.60 and are due to expire on February 23, 2023 (see

February 23, 2021 News Release).

About Lithium Chile

Lithium Chile is advancing a lithium property portfolio consisting of 69,200 hectares covering

sections of 10 salars and two laguna complexes in Chile and 23,300 hectares in Argentina.

Lithium Chile also owns 5 properties, totaling 20,429 hectares, that are prospective for gold, silver

and copper. Exploration efforts are continuing on Lithium Chile’s Carmona gold/silver/copper

property which lies in the heart of the Chilean mega porphyry gold/ silver/copper belt.

Lithium Chile’s common shares are listed on the TSX-V under the symbol “LITH” and on the OTC-

BB under the symbol “LTMCF”.

To find out more about Lithium Chile Inc., please contact Steven Cochrane, President and CEO via

email: [email protected], Jose de Castro Alem, Argentina Manager via email

[email protected] or Michelle DeCecco, Vice President of Corporate Development via

email [email protected] or at 587-393-1990.

NEITHER THE TSX VENTURE EXCHANGE NOR ITS REGULATION SERVICES PROVIDER (AS THAT TERM IS DEFINED IN THE POLICIES OF THE

TSX VENTURE EXCHANGE) ACCEPTS RESPONSIBILITY FOR THE ADEQUACY OR ACCURACY OF THIS RELEASE.

Forward Looking Statements: This news release may contain certain forward-looking information and forward-

looking statements within the meaning of applicable securities legislation (collectively "forward-looking

statements"). Generally, forward-looking statements can be identified by the use of forward-looking terminology

such as "expected", "anticipated", "aims to", "plans to" or "intends to" or variations of such words and phrases or

statements that certain actions, events or results "will" occur. In particular, this news release contains forward-

looking statements relating to, among other things: the estimates in the Report, future drilling programs and the

results thereof. Such forward-looking statements are based on various assumptions and factors that may prove to be

incorrect, including, but not limited to, factors and assumptions with respect to: the general stability of the economic

and political environment in which the Company operates; the timely receipt of required regulatory approvals; the

ability of the Company to obtain future financing on acceptable terms; currency, exchange and interest rates;

operating costs; the success the Company will have in exploring its prospects and the results from such prospects.

You are cautioned that the foregoing list of material factors and assumptions is not exhaustive. Although the

Company believes that the assumptions and factors on which such forward-looking statements are based are

reasonable, undue reliance should not be placed on the forward-looking statements because the Company can give no

assurance that they will prove to be correct or that any of the events anticipated by such forward-looking statements

will transpire or occur, or if any of them do so, what benefits the Company will derive there from. Actual results

could differ materially from those currently anticipated due to a number of factors and risks including, but not

limited to: fluctuations in market conditions, including securities markets; economic factors; the risk that the new

lithium exploration tender process does not yield the anticipated benefits to the Company, if at all; the risk that the

Offering will not be completed as anticipated or at all, including the risk that the Company will not receive the

approvals necessary in connection with the Offering; and the impact of general economic conditions and the COVID-

19 pandemic. The Company does not undertake to update any forward-looking statements herein, except as required

by applicable securities laws. All forward-looking statements contained in this news release are expressly qualified by

this cautionary statement.