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GSVR.V ·

~GSilver Discovers High-Grade Historical Tailings Material at El Cubo~ ~Assays 727 gpt AgEq over 1.2m and 711 gpt AgEq over 1.0m ~

Drill Results

TSX-V: GSVR OTCQX: GSVRF

~GSilver Discovers High-Grade Historical Tailings Material at El Cubo~

~Assays 727 gpt AgEq over 1.2m and 711 gpt AgEq over 1.0m ~

June 22, 2022– Vancouver, British Columbia – Guanajuato Silver Company Ltd. (the “Company” or “ GSilver”)

(TSXV:GSVR)(OTCQX:GSVRF) is pleased to report the discovery of high-grade gold and silver material in a n

historical tailings area at the Company’s wholly owned El Cubo Mine Complex in Guanajuato, Mexico.

Highlights:

• A 43,000 sq. meter, 1.0m-1.5m thick layer of high-grade surface material has been identified from a retired

tailings facility named ‘Mastrantos IV’.

• 134 shallow drillholes, totalling 220.5 drilled meters (holes to approximately 2.0m depth), were completed

at Mastrantos IV this year; the best results included Drillhol e #164 grading 727gpt AgEq over 1.2m and

Drillhole# 166 grading 711 g pt AgEq over 1 .0m. Over 95% of the d rillholes encountered significant

mineralization.

• The majority of this mineralization exists as free -gold; GSilver has tested several different gravitational

separation procedures in order to extract the gold and silver from this material. Final assessments on the

exact method the Company will use to process this material will be decided upon shortly.

Commenting on this news, James Anderson, Chairman & CEO said, “Our intention is to add additional silver and

gold concentrate production through an independent gravity separation circuit. This will allow us to expand overall

production at El Cubo without interfering with the regular flow of material through our processing facility. GSilver’s

ability to identify and then rapidly act upon this opportunity is demonstrative of the technical quality of our

Mexican operating team . Going forward, we plan to investigate and subsequently exploit similar development

opportunities that we believe exist within the Guanajuato mining district, where processing of precious metals

has been ongoing for over 450 years.”

The Mastrantos IV tailings facility is located approximately 3km from the El Cubo mill and had an operational

history dating principally between 1986 to 2003, during which time the price of gold generally traded below

US$400 per ounce. Also, most of the Mastrantos IV material comes from El Cubo’s Santa Cecilia area which at that

time was encountering bonanza gold grades . These combined circumstances may have contribute d to the low

gold recoveries and the high-grade values left in the tailings.

The target area at Mastrantos IV is a gold and silver mineralized layer starting at surface and extending to

approximately 1.5 meters in depth; a total of 134 shallow holes (drilled to approximately 2.0m total depth) were

drilled over an area of more than 43,000 sq. meters. Silver equivalent (AgEq) results for each hole are included in

Figures 1 and 3 below; higher grades of greater than 250 gpt AgEq are common and make up the majority of the

drillholes that define this mineralized layer . GSilver has not undertaken a NI 43 -101 resource estimate for this

mineralized material; however if metallurgical tests support economic viability, GSilver plans to begin processing

the Mastrantos IV material as soon as practicable.

2

Preliminary testing to date, which has included a bulk sample and numerous metallurgical trials completed in

conjunction with the University of Guanajuato’s School of Mines, has demonstrated encouraging results. Once

final metallurgical tests are completed, the Company plans to extract the gold and silver content from Mastrantos

IV using a gravity extraction circuit.

The El Cubo Mine has been in almost continuous operations for the past 200 years. GSilver will continue to

investigate additional opportunities for tailings reprocessing from other tailing facilities located on its properties

- many of which pre-date Mastrantos IV.

Figure 1 – Plan View of Mastrantos IV Showing Assay Results in AgEq.

Figure 2 – Plan View of Mastrantos IV Showing Drillhole Collar Locations.

3

Figure 3 – Table of assay results for 134 shallow drill holes (101 to 248), all results drilled from surface.

4

Note: All silver equivalent (AgEq) values are calculated based on a long-term gold to silver price ratio of 80 :1 as

used by mineral industry advisors, Behre Dolbear and Company (USA), Inc., in the Company’s NI 43-101 PEA report

with the effective date of January 31, 2021; a copy of which is available for review on SEDAR.

Sampling and quality assurance/quality control

Drill core was first reviewed by a Company geologist , who identified and marked intervals for sampling. The

marked sample intervals were then cut in half; half of the core was left in plastic bag, and the other half was placed

in additional plastic bags, sealed and labeled. Intervals and unique sample numbers are recorded on the drill logs

and the samples are sequenced with standards and blanks inserted according to a predefined QA/QC procedure.

The samples are maintained under security on site until they are shipped to the analytical lab. The analytical work

reported on herein was performed by Corporacion Quimica Platinum S.A de C.V., Silao, Guanajuato, Mexico

(Uncertified Laboratory). To validate our assay results and our preparation procedures , GSilver sends additional

random samples representing approximately 20% of all analytical samples to Bureau Veritas in Hermosillo, Sonora,

Mexico. Bureau Veritas is an ISO/IEC (International Organization for Standardization/International

Electrotechnical Commission) geo-analytical laboratory and is independent of GSilver and its "qualified person".

Core samples were subject to crushing at a minimum of 70 per cent passing two mil limeters, followed by

pulverizing of a 250 -gram split to 85 per cent passing 75 microns. Gold determination was via standard atomic

absorption (AA) finish 30 -gram fire assay (FA) analysis, in addition to silver and 34 -element using fire assay and

gravimetry termination. Following industry-standard procedures, blank and standard samples were inserted into

the sample sequence and sent to the laboratory for analysis. Data verification of the analytical results included a

statistical analysis of the standards and blanks that must pass certain parameters for acceptance to ensure

accurate and verifiable results. GSilver detected no significant QA/QC issues during review of the data and is not

aware of any sampling, recovery or other factors that could materially affect the accuracy or reliability of the data

referred to herein.

Hernan Dorado Smith, a director and officer of GSilver and a "qualified person" as defined by National Instrument

43-101, Standards of Disclosure for Mineral Projects, has approved the scientific and technical information

contained in this news release.

About Guanajuato Silver Co. Ltd.:

GSilver mines and processes silver and gold concentrate from its El Cubo mine and mill. The Company continues

to delineate for additional silver and gold resources through underground drilling at El Cubo and its nearby El

Pinguico project. Both projects are located within 11km of the city of Guanajuato, Mexico, which has

an established 480-year mining history.

ON BEHALF OF THE BOARD OF DIRECTORS

"James Anderson"

Chairman and CEO

For further information regarding Guanajuato Silver Company Ltd., please contact:

JJ Jennex, Communications Manager, +1 (604) 723-1433

Email: [email protected]

Continue to watch our progress at: www.GSilver.com

Neither the TSX Venture Exchange nor its Regulation Services Provider (as that term is defined in the

policies of the TSX Venture Exchange) accepts responsibility for the adequacy or accuracy of this

release.

Forward-Looking Information and Statements

5

This news release contains certain forward-looking information and statements, which relate to future events or future

performance including, but not limited to, the potential quantity, grades and recovery rates of mineralized material contained

within the historic ‘Mastrantos IV’ tailings facility and the potential for additional mineralized material in other historic tailings

facilities at El Cubo or elsewhere, the Company’s plan to begin processing of mineralized material from ‘Mastrantos IV’ upon

receipt of favorable metallurgical test results, the gravitational separation method to be used and the estimated timing

thereof, and the Company’s expectations for expanding overall production at El Cubo without interfering with the current

flow of materials through the El Cubo processing facility and generating additional revenue from Mastrantos IV and

potentially other historic tailings facilities in and about Guanajuato, Mexico. Such forward-looking statements and

information reflect management's current beliefs and are based on information currently available to and assumptions made

by the Company; which assumptions, while considered reasonable by the Company, are inherently subject to significant

operational, business, economic and regulatory uncertainties and contingencies. These assumptions include: our estimates

of the overall volume of mineralized material at Mastrantos IV and the grades thereof and the assumptions upon which they

are based, including geotechnical and metallurgical characteristics of the mineralized material conforming to sampled results

and metallurgical performance; tonnage of mineralized material to be mined and processed; resource grades and recoveries;

assumptions and discount rates being appropriately applied to production estimates; success of the Company’s mining

operations at Mastrantos IV; prices for silver and gold remaining as estimated; currency exchange rates remaining as

estimated; availability of funds for development of Mastrantos IV, capital, decommissioning and reclamation estimates;

prices for energy inputs, labour, materials, supplies and services (including transportation) remaining as estimated; no labour-

related disruptions; no unplanned delays or interruptions in scheduled construction and production; all necessary permits,

licenses and regulatory approvals are received in a timely manner; and the ability to comply with environmental, health and

safety laws. The foregoing list of assumptions is not exhaustive. Readers are cautioned that such forward-looking statements

and information are neither promises nor guarantees, and are subject to risks and uncertainties that may cause future results

to differ materially from those expected including, but not limited to, market conditions, rising inflation, supply chain

disruptions, availability of financing, currency rate fluctuations, actual results of development and production activities, actual

resource grades and recoveries of silver and gold, unanticipated geological or structural formations and characteristics,

environmental risks, future prices of silver, gold and other metals, operating risks, accidents, labour issues, equipment or

personnel delays, delays in obtaining governmental or regulatory approvals and permits, inadequate insurance, and other

risks in the mining industry. There are no assurances that GSilver will be able to develop and produce concentrate from the

historic tailings at Mastrantos IV to deliver the tonnage, grades, recoveries, and revenue from precious metals concentrate

sales at the costs and within the timetable anticipated. In addition, GSilver’s plan to begin processing mineralized material

from Mastrantos IV following receipt of favorable metallurgical results is not based on a feasibility study of mineral reserves

demonstrating economic and technical viability and therefore is subject to increased uncertainty and risk of failure, both

economically and technically. Mineralized materials that are not Mineral Reserves do not have demonstrated economic

viability, are considered too speculative geologically to have the economic considerations applied to them, and may be

materially affected by environmental, permitting, legal, title, socio-political, marketing, and other relevant issues. There are

no assurances that the processing of mineralized material from Mastrantos IV will generate revenues or positive cash flow in

the amounts anticipated or at all. There is also uncertainty about the ongoing spread of COVID-19, the war in Ukraine, rising

inflation and interest rates (both domestically and abroad) and the impact they will have on the Company's operations, supply

chains, ability to access El Cubo and/or El Pinguico or procure equipment, supplies, contractors and other personnel or raise

capital on a timely basis or at all and economic activity in general. All the forward-looking statements and information made

in this news release are qualified by these cautionary statements and those in our continuous disclosure filings available on

SEDAR at www.sedar.com. The forward-looking statements and information are made as of the date hereof and the Company

does not assume any obligation to update or revise them to reflect new events or circumstances save as required by law.