Arizona Silver Reports Good GOLD Grades ON Undrilled Segment of the Philadelphia Vein, Arizona

#970 – 777 Hornby Street, Vancouver, B.C. V6Z 1S4

T: 604.559.3511 x150 / F : 604.559.3501 / W : www.arizonasilverexploration.com

NEWS RELEASE

ARIZONA SILVER REPORTS GOOD GOLD GRADES ON UNDRILLED SEGMENT OF THE

PHILADELPHIA VEIN, ARIZONA

Vancouver, British Columbia , October 14, 20 21 – Arizona Silver Exploration Inc . (TSXV:

AZS) (OTCQB:AZASF) is pleased to announce the results of surface channel sampling completed on an

undrilled 300 meter segment of the Philadelphia-Perry vein at the Philadelphia project. Drilling of this segment

known as the “Gap” is scheduled for November-December when drill road access is completed.

Channel Samples up to 6.57 gpt gold across 2.44 meters and 5.9 gpt gold across 1.2 metres

Assays results are in on 95 channel samples taken in August along an undrilled portion of the Philadelphia -

Perry vein. Channel samples across and along the vein have returned good gold values at several locations,

including 3.1 gpt Au across 3.3 metres of vein and 5.9 gpt Au across 1.2 meters of vein. In addition, sampling

returned 6.57 gpt Au across 2.44 metres of hanging wall volcanics between our recently completed drill

sections. A summary table is provided below. A sample location map is posted to the web site

https://arizonasilverexploration.com/philadelphia/

Greg Hahn, VP-Exploration states “These results are particularly significant as this area represents

a 300-metre-long drilling Gap between two recent drill sections that returned excellent results for us.

Based on vein textures we expect the “boiling zone” to begin some 100 metres below surface. Within

that zone our emerging experience will be for us to intersect good grades both in the vein and the

stockwork vein system adjacent to it. Clearly, these results provide strong encouragement for our

upcoming road construction and core drilling program both within the Gap and along strike to the

north. The opportunity to drill an untested 1500-metre-long extension of the vein system to the south

remains open to us.”

Table of Highlights of Channel Samples

Sample

Number Au gpt Length Lithology Comments

(m)

PH21-MS-66 4.07 1.52 granite 10% Vn Qtz

PH21-MS-67 0.81 2.44 granite 20% Vn Qtz

PH21-MS-68 0.77 1.83 rhyolite VG 75% Vn Qtz

PH21-MS-70 2.21 1.22 Breccia Sample of Hydrothermal Breccia. 90% Vn Qtz. VG

PH21-MS-71 3.27 0.91 rhyolite 50% vn Qtz

PH21-MS-72 0.30 1.52 rhyolite 30% Vn Qtz

PH21-MS-76 6.38 1.83 granite 5% Vn Qtz

PH21-MS-77 0.39 2.44 granite 20% vn Qtz

PH21-MS-79 0.44 2.44 granite 20% Vn Qtz

PH21-MS-80 0.61 1.83 granite VG 20%vn qtz

PH21-MS-81 0.32 1.22 granite 20%vn qtz

PH21-MS-84 0.51 1.22 Breccia 40% Vn Qtz, 30% dark Cc

PH21-MS-85 0.32 0.91 granite 5% Vn Qtz, 1% Dark Cc

#970 – 777 Hornby Street, Vancouver, B.C. V6Z 1S4

T: 604.559.3511 x150 / F : 604.559.3501 / W : www.arizonasilverexploration.com

PH21-MS-86 0.32 1.52 granite 5% Vn Qtz, 1% Dark Cc

PH21-MS-87 0.59 1.83 rhyolite 50% Vn qtz, 10% Dark Cc

PH21-MS-98 0.96 1.22 mixed 40% vn qtz

PH21-MS-101 0.44 0.91 rhyolite 1% vn Qtz

PH21-MS-102 5.90 1.22 rhyolite 10% vn qtz

PH21-MS-104 0.31 3.05 grn. rhyolite line sample

PH21-MS-106 0.46 3.05 grn. rhyolite line sample

PH21-MS-107 3.30 3.05 grn. rhyolite line sample

PH21-MS-108 1.56 3.66 grn. rhyolite line sample

PH21-MS-110 0.60 0.61 grn. rhyolite 70% Vn Qtz

PH21-MS-111 1.56 0.61 volcanics 10% vn qtz

PH21-MS-113 6.57 2.44 volcanics Ladder Pit. 1% Vn Qtz

PH21-MS-114 0.38 1.22 volcanics 2% vn Qtz

PH21-MS-115 1.55 3.05 volcanics 2% vn Qtz

PH21-MS-116 1.24 3.05 rhyolite 2% vn Qtz

PH21-MS-117 1.20 3.05 rhyolite 5% vn Qtz

PH21-MS-118 1.03 1.83 grn. rhyolite 1% Vn Qtz

PH21-MS-119 0.61 1.83 granite 20% vn qtz. Prospect

PH21-MS-120 0.14 3.05 granite 3% Vn Qtz

PH21-MS-121 0.25 3.05 granite 15% vn Qtz

PH21-MS-122 0.10 3.05 granite 10% Vn Qtz

PH21-MS-126 0.69 0.61 granite 20% Vn Qtz

PH21-MS-127 0.57 0.76 andesite 10% Vn Qtz

PH21-MS-128 0.94 3.05 granite 10% Vn Qtz Prospect

PH21-MS-131 1.45 0.46 granite 80% Vn qtz

PH21-MS-139 1.13 3.05 granite 3% Vn Qtz

PH21-MS-140 0.44 2.44 granite 3% Vn Qtz

PH21-MS-153 2.81 0.61 andesite 3% Qtz vng. Tad dike at hidden shaft

PH21-MS-154 1.95 0.76 rhyolite 10% vn Qtz

QA/QC Program

All assaying was conducted by ALS Global, an independent analytical laboratory. RC cuttings were delivered

to the ALS delivery truck on site and trucked to the ALS sample preparation facility in Tucson, Arizona, where

the samples are inventoried, dried, cr ushed and pulverized. Pulverized splits are sent to the ALS analytical

facility in Vancouver, British Columbia for analyses. All material handling is done under a strict chain of

custody protocol. Gold is determined by fire assay with an AA finish and si lver is determined by ICP -MS

methods within a 31-element suite.

The Company maintains its own program of inserting Standard Reference material in the form of standards

and blanks to the sampling stream, prior to being shipped to ALS's preparation facility in Tucson, Arizona, in

addition to the independent QA/QC protocols of ALS Global.

Qualified Person

Gregory Hahn, VP -Exploration and a Certified Professional Geologist (#7122) is a Qualified Person under

National Instrument 43-101 ("NI 43-101") and has reviewed and approved the technical information contained

in this news release.

About Arizona Silver Exploration Inc.

#970 – 777 Hornby Street, Vancouver, B.C. V6Z 1S4

T: 604.559.3511 x150 / F : 604.559.3501 / W : www.arizonasilverexploration.com

Arizona Silver is a young exploration company focused on exploring gold-silver properties in western Arizona

and Nevada. The flagship asset is the Philadelphia property but the Company plans to continue to drill test the

Ramsey Silver Mine property located a short distance east of Quartzsite, Arizona. The Company has recently

received a positive Record of Decision on its Notice of Intent to drill an initial twelve exploration holes on its

recently acquired Silverton gold-silver property that hosts Carlin-type targets. Drilling there will be scheduled

as time and equipment allow.

Please refer to our web site for all news and updated property information.

www.arizonasilverexploration.com

On behalf of the Board of Directors:

ARIZONA SILVER EXPLORATION INC.

Mike Stark, President and CEO, Director

Phone: (604) 833-4278

Neither the TSX Venture Exchange nor its Regulation Services Provider (as that term is defined in the policies of the TSX

Venture Exchange) accepts responsibility for the adequacy or accuracy of this releas e.

CAUTION CONCERNING FORWARD-LOOKING STATEMENTS

This news release includes certain forward -looking statements or information. All statements other than statements of

historical fact included in this release are forward -looking statements that involve various risks and uncertainties.

Forward-looking statements in this news release include statements in relation to the timing, cost and other aspects of the

2020-2021 exploration program; the potential for development of the mineral resources; the potential mineralization and

geological merits of the exploration properties; and other future plans, objectives or expectations of the Company. There

can be no assurance that such statements will prove to be accurate and actual results and future events could differ

materially from those anticipated in such statements. Important factors that could cause actual results to differ materially

from the Company's plans or expectations include the risk that actual results of current and planned exploration activities,

including the results of the Company's 2021 drilling pr ogram(s) on its pro perties, will not be consistent with the

Company's expectations; the geology, grade and continuity of any mineral deposits and the risk of unexpected variations

in mineral resources, grade and/or recovery rates; fluctuating metals prices ; possibility of accidents, equipment

breakdowns and delays during exploration; exploration cost overruns or unanticipated costs and expenses; uncertainties

involved in the interpretation of drilling results and geological tests; availability of capital an d financing required to

continue the Company's future exploration programs and preparation of geological reports and studies; delays in the

preparation of geological reports and studies; the metallurgical characteristics of mineralization contained within the

exploration properties are yet to be fully determined; general economic, market or business conditions; competition and

loss of key employees; regulatory changes and restrictions including in relation to required permits for exploration

activities (including drilling permits) and environmental liability; timeliness of government or regulatory approvals; and

other risks detailed herein and from time to time in the filings made by the Company with securities regulators. In

connection with the forward -looking information contained in this news release, the Company has made numerous

assumptions, including that the Company's 2021 programs would proceed as planned and within budget. The Company

expressly disclaims any intention or obligation to update or revis e any forward-looking statements whether as a result of

new information, future events or otherwise, except as otherwise required by applicable securities legislation.