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Golden Minerals Drills 18m Grading 2.9 g/t Gold at Rodeo Gold-Silver Mine

Drill Results

Page 1 of 5

G O L D E N M I N E R A L S C O M P A N Y

350 Indiana Street – Suite 650 – Golden, Colorado 80401 – Telephone (303) 839-5060

Golden Minerals Drills 18m Grading 2.9 g/t Gold at Rodeo

Gold-Silver Mine

GOLDEN, CO - /BUSINESS WIRE/ - October 19, 2021 – Golden Minerals Company (“Golden Minerals”, “Golden” or

the “Company”) (NYSE-A: AUMN and TSX: AUMN) is pleased to announce assay results from 25 recently completed

reverse circulation (“RC”) drill holes at its Rodeo gold-silver mine located in Durango State, Mexico.

The company has drilled 47 RC holes totaling 3 ,187m, focusing on resource expansion and e xploration of several

targets located adjacent to the open pit. The reverse circulation drilling was completed in early October.

Highlights from the initial RC holes include:

• RRC_021_018 returned 18m grading 2.3 g/t Au and 5 g/t Ag within 54m grading 1.0 g/t Au and 5 g/t Ag

• RRC_021_020 returned 8m grading 2.4 g/t Au and 16 g/t Au within 26m grading 1.7 g/t Au and 12 g/t Ag

• RRC_021_021 returned 24m grading 2.2 g/t Au and 18 g/t Ag within 56m grading 1.3 g/t Au and 17 g/t Ag

• RRC_021_022 returned 8m grading 3.9 g/t Au and 5 g/t Ag within 56m grading 1.0 g/t Au and 4 g/t Ag

• RRC_021_025 returned 18m grading 2.9 g/t Au and 11 g/t Ag within 52m grading 1.3 g/t Au and 6 g/t Ag

Drilling has intersected several wide zones of disseminated gold mineralization and has identified several additional

high-grade zones that appear to be hosted in a series of silicified structures running parallel to the high -grade gold

zones currently being exploited. The mineralization in these new zones is very similar to the material currently being

mined and consists of highly silicified epithermal veins and breccias hosted in felsic volcanic rocks.

Warren Rehn, President and Chief Executive Officer of Golden Minerals, commented, "The initial RC drill results are

very positive. The gold-bearing intervals expand on the known zones of mill-grade gold mineralization to the south

of the current pit and indicate that there is strong potential for Rodeo to h ost additional profitable tonnage, at

current prices, to the south and west of the current pit.”

Page 2 of 5

G O L D E N M I N E R A L S C O M P A N Y

350 Indiana Street – Suite 650 – Golden, Colorado 80401 – Telephone (303) 839-5060

Figure 1: Completed RC drill holes, Rodeo Gold Mine, Durango

Page 3 of 5

G O L D E N M I N E R A L S C O M P A N Y

350 Indiana Street – Suite 650 – Golden, Colorado 80401 – Telephone (303) 839-5060

Significant results are summarized in the table below, with complete results available on the Company website. [link]

Note: Intervals in the table represent drilled length. It is expected that true thickness is approximately 80% of drilled

length as drill holes were drilled perpendicular to the gold mineralization that dips at approximately 25 degrees to

the northeast. Intervals and grades have been rounded to either one or two decimal places.

Hole_ID From To Interval Au_g/t Ag_g/t

RRC_021_001 14 28 14 0.58 2.2

RRC_021_002

RRC_021_003

RRC_021_004 24 74 50 0.69 23.2

including 48 54 6 1.41 27.8

RRC_021_005 48 68 20 1.01 34.9

including 66 68 2 2.73 66.3

RRC_021_006 - 4 4 0.92 10.2

RRC_021_007

RRC_021_008 32 64 32 0.59 1.3

including 36 46 10 1.01 2.0

RRC_021_009 30 44 14 0.87 3.1

RRC_021_010 - 36 36 0.93 3.1

including - 8 8 2.15 2.0

RRC_021_011 6 51 45 0.77 8.9

including 8 18 10 1.20 3.5

including 42 48 6 1.34 24.3

RRC_021_012 12 64 52 0.98 9.1

including 12 28 16 1.89 7.8

RRC_021_013 10 84 74 0.77 18.2

including 10 34 24 1.14 6.4

RRC_021_014 4 66 62 0.76 10.2

including 18 36 18 1.05 5.0

including 46 56 10 1.17 22.9

RRC_021_015 2 22 20 0.77 6.4

including 4 18 14 1.00 7.0

RRC_021_016 - 40 40 1.09 17.4

including 8 30 22 1.67 22.9

RRC_021_017 - 12 12 1.12 7.8

& 32 75 43 0.55 19.6

RRC_021_018 - 54 54 1.00 4.7

including 2 20 18 2.33 4.6

RRC_021_019 4 46 42 0.82 2.7

including 14 20 6 1.43 2.6

RRC_021_020 28 54 26 1.67 12.1

including 30 38 8 2.02 14.0

including 44 52 8 2.35 15.9

RRC_021_021 - 56 56 1.28 16.5

including - 24 24 2.17 17.9

RRC_021_022 - 56 56 1.00 4.4

including 10 18 8 3.92 4.6

RRC_021_023 14 62 48 0.56 6.0

including 22 54 32 0.65 6.0

RRC_021_024 10 54 44 0.67 3.1

including 28 32 4 1.56 4.1

RRC_021_025 8 60 52 1.33 6.0

including 16 34 18 2.90 11.0

No significant results

No significant results

No significant results

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G O L D E N M I N E R A L S C O M P A N Y

350 Indiana Street – Suite 650 – Golden, Colorado 80401 – Telephone (303) 839-5060

About Rodeo

Rodeo is a gold -silver open pit mine located in Durango State, Mexico. Production began in January 2021, with

material being trucked to the Company’s oxide mill at the Velardeña Properties located around 115 kilometers away

via road. Rodeo’s current expected life per the terms of an independently prepared, NI 43-101-compliant Preliminary

Economic Assessment (April 2020) is 2.5 years.

Review by Qualified Person and Quality Control

The technical contents of this press release have been reviewed by Matthew Booth, a Qualified Person for the

purposes of NI 43 -101. Mr. Booth has over 17 years of mineral exploration experience and is a Qualified Person

member of the American Institute of Professional Geologists (CPG 12044).

To ensure reliable sample results, Golden Minerals uses a quality assurance/quality control program that monitors

the chain of custody of samples and includes the insertion of blanks, duplicates, and reference standards in each

batch of samples.

Quality Assurance / Quality Control

RC drilling was conducted with a Prospector W750 articulated carrier mounted RC drill rig provided by Major Drilling.

Holes were drilled at an azimuth of 240° or 60o and a dip ranging from -45o to -60°. Drill holes were drilled to depths

ranging FROM 36m to 108m. No water was encountered during drilling. Holes were positioned with a hand-held GPS

(accuracy +/- 5 meters) and later surveyed with a Differential GPS once the hole was competed. Sampling was

conducted from the drill rig cyclone at 2-meter drill intervals. Each 2-meter sample was riffle split to approximately

6 kilograms samples for assay. RC chips were logged at the drill rig and a small, 100g sample was collected and logged

and stored in chip-trays onsite.

Drill-core, reverse circulation drill chips and rock samples were shipped to ALS Chemex sample preparation facility

in Chihuahua, Chihuahua, Mexico for sample preparation and for analysis at the ALS laboratory in North Vancouver.

The ALS Chihuahua and North Vancouver facilities are ISO 9001 and ISO/IEC 17025 certified. ALS Global in North

Vancouver, British Columbia, Canada, is a facility certified as ISO 9001:2008 and accredited to ISO/IEC 17025:2005

from the Standards Council of Canada.

The samples were crushed to 70% passing 2mm (PREP-31) and a split of up to 250 grams pulverized to 85% passing

75 micrometres (-200 mesh). The sample pulps and crushed splits were transferred internally to ALS Global’s North

Vancouver, Canada analytical facility for gold and multi-element analysis. Pulps (30gram split) are submitted for Au

analysis by Fire Assay with Atomic Absorption finish (Au -AA23) and silver samples were analyzed by an atomic

absorption (Ag-AA45).

Over-limit Au and Ag samples are analyzed by Fire Assay with Gravimetric Finish Ore Gr ade (Au-GRA22 and Ag -

GRA21). Overlimit base metals are analyzed by Four Acid Digestion followed by Ore Grade Inductively Coupled

Plasma Atomic Emission Spectrometry (ICP-AES) for Cu, Pb and Zn (Cu-OG62, Pb-OG62, Zn-OG62).

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G O L D E N M I N E R A L S C O M P A N Y

350 Indiana Street – Suite 650 – Golden, Colorado 80401 – Telephone (303) 839-5060

In-house quality control samples (blanks, standards, duplicates, preparation duplicates) were inserted into the

sample set by Golden Minerals. ALS Global conducts its own internal QA/QC program of blanks, standards and

duplicates, and the results were provided with the Company sample cer tificates. The results of the ALS control

samples were reviewed by Golden Minerals and the Company’s QP and evaluated for acceptable tolerances.

All sample and pulp rejects are stored at the Company’s secure warehouse in Velardeña, Durango pending full review

of the analytical data, and future selection of pulps for independent third-party check analyses, if required.

About Golden Minerals

Golden Minerals is a growing gold and silver producer based in Golden, Colorado. The Company is primarily focused

on producing gold and silver from its Rodeo Mine and advancing its Velardeña Properties in Mexico and, through

partner funded exploration, its El Quevar silver property in Argentina, as well as acquiring and advancing selected

mining properties in Mexico, Nevada and Argentina.

Forward-Looking Statements

This press release contains forward-looking statements within the meaning of Section 27A of the Securities Act of

1933, as amended and Section 21E of the Securities Exchange Act of 1934, as amended, and applicable Canadian

securities legislation, including statements regarding the Company’s expectations for the additional high-grade

zones of disseminated gold mineralization that the Company has identified at Rodeo, estimates of true thickness of

the gold mineralization at previous drill holes , and anticipated potential for Rodeo to host additional profitable

tonnage. These statements are subject to risks and uncertainties, including the reasonability of the economic

assumptions at the basis of the results of the Rodeo project Preliminary Economic Assessment and technical report;

changes in interpretations of geological , geostatistical, metallurgical, mining or processing information; and

interpretations of the information resulting from exploration, analysis or mining and processing experience. Golden

Minerals assumes no obligation to update this information. Additional risks relating to Golden Minerals may be

found in the periodic and current reports filed with the SEC by Golden Minerals, including the Company’s Annual

Report on Form 10-K for the year ended December 31, 2020.

For additional information please visit http://www.goldenminerals.com/ or contact:

Golden Minerals Company

Karen Winkler, Director of Investor Relations

(303) 839-5060

SOURCE: Golden Minerals Company